African Journal of
Pure and Applied Chemistry

  • Abbreviation: Afr. J. Pure Appl. Chem.
  • Language: English
  • ISSN: 1996-0840
  • DOI: 10.5897/AJPAC
  • Start Year: 2007
  • Published Articles: 357

Full Length Research Paper

Spectrophotometric studies of charge transfer complex of 8-hydroxyquinoline with 1,4-benzoquinone

Asmaa A. Ibrahim
Department of Chemistry, Faculty of Science, South Valley University, Aswan 81528, Egypt.
Email: [email protected]

  •  Accepted: 14 December 2011
  •  Published: 30 December 2011

Abstract

The interaction between donor 8-hydroxyquinoline (HQ) and π - acceptor 1, 4-benzoqinone (BQ) has been studied in the solution as well as in the solid state. Infrared spectroscopic data indicate that a charge transfer interaction between the donor and acceptor are due to π → π*/ n → π* transition by the formation of radical ion pairs. In solution state, the formation constant, the extinction coefficient, the free energy and transition energy of the resulting charge transfer complex (CTC) were determined. The optimum experimental conditions, such as time, temperature and solvents for the CTC formation were established.

 

Key words: 8–Hydroxyquinoline, 1, 4–benzoqinone, the formation constant for the charge transfer complex and infrared spectroscopic.