African Journal of
Pure and Applied Chemistry

  • Abbreviation: Afr. J. Pure Appl. Chem.
  • Language: English
  • ISSN: 1996-0840
  • DOI: 10.5897/AJPAC
  • Start Year: 2007
  • Published Articles: 357

Full Length Research Paper

Multiple regression analyses of kinetics of aquation reactions of some chromium (III) – alkyl amine complexes in mixed solvent media- A study of solvation mechanics

A. Rajendran1* and K. Anbalagan2
1Department of Chemistry, Sir Theagaraya College, Chennai-600 021,Tamil Nadu, India. 2Department of Inorganic Chemistry, Pondicherry University, Puducherry-605 014, India
Email: [email protected]

  •  Accepted: 23 February 2011
  •  Published: 30 April 2011

Abstract

Molecular dynamics of the aquation reactions of the complexes  [Cr(en)2Cl2]Cl,[Cr(tn)2Cl2]Cl,[Cr(tetren)Cl]Cl2, [Cr(pn)2Cl2]Cl, [Cr(trien)Cl2]Cl and [Cr(dien)Cl3] have been extensively studied in mixed solvent media. Kinetics and thermodynamic parameters have been evaluated and the results are interpreted carefully in the light of statistical and regression models.

 

Key words: Cr (III) complexes, molecular dynamics, aquation reaction, kinetic parameters, thermodynamic parameter, statistical model, regression model.