African Journal of
Pure and Applied Chemistry

  • Abbreviation: Afr. J. Pure Appl. Chem.
  • Language: English
  • ISSN: 1996-0840
  • DOI: 10.5897/AJPAC
  • Start Year: 2007
  • Published Articles: 354

Full Length Research Paper

Kinetic, mechanism and spectral studies of bis (dibenzoyl-methane) copper (II) complex and its adducts

Mary Adelaide Oladipo1, Olugbenga Solomon Bello1* and Adewumi Idowu Adeagbo2
1Department of Pure and Applied Chemistry, Ladoke Akintola University of Technology, P. M. B 4000, Ogbomoso, Oyo State, Nigeria. 2Department of Chemistry, Emmanuel Alayande College of Education Oyo, Oyo State, Nigeria.
Email: [email protected]

  •  Accepted: 12 January 2012
  •  Published: 10 February 2012

Abstract

The copper (II) complex of 1, 3-diphenyl-1, 3-propanedione (dbm) and its adducts with 2, 2-bipyridine (bipy) and 1, 10-phenantroline (phen) were synthesized. They were characterized by micro analytical data, infrared and ultraviolet (UV)-visible spectra and magnetic susceptibility data. The kinetics of the formation of the complex follows a rapid pre-equilibrium in which the rate is independent of the metal concentration, suggesting an interchange associative mechanism.

 

Key words: Copper (II)-adducts, kinetics, mechanism of formation, interchange associative mechanism.