International Journal of
Physical Sciences

  • Abbreviation: Int. J. Phys. Sci.
  • Language: English
  • ISSN: 1992-1950
  • DOI: 10.5897/IJPS
  • Start Year: 2006
  • Published Articles: 2572

Full Length Research Paper

Equilibrium sorption isotherm for lead (Pb) ions on hydrogen peroxide modified rice hulls

E.O. Aluyor1*, I.O. Oboh2 and K.O. Obahiagbon1
1Department of Chemical Engineering, University of Benin, Benin City Nigeria. 2Department of Chemical and Petroleum Engineering, University of Uyo, Uyo, Nigeria.
Email: [email protected]

  •  Accepted: 13 July 2009
  •  Published: 31 August 2009

Abstract

Modified rice hulls system for removing Pb (II) from aqueous solutions has been investigated. Rice hulls are agricultural waste product. The experimental condition was the modification of the rice hulls (sorbent) with different concentrations of hydrogen peroxide solution. The experimental results were fitted to the Langmuir and Freundlich isotherms to obtain the characteristic parameters of each model. The Langmuir isotherm was found to well represent the results. The maximum sorption capacities of various concentrations of hydrogen peroxide modified rice hulls were 2.57, 3.15, 5.15, 8.57, 10.97 and 11.88 mg/g for 0.1, 0.3, 0.6, 0.9, 1.2 and 1.5 M hydrogen peroxide solution respectively.It was noted that increasing the concentration for modification resulted in a higher metal uptake per unit weight of the modified rice hulls.

 

Key words: Modified, Langmuir, Freundlich, hydrogen peroxide, rice hulls, lead.