International Journal of
Physical Sciences

  • Abbreviation: Int. J. Phys. Sci.
  • Language: English
  • ISSN: 1992-1950
  • DOI: 10.5897/IJPS
  • Start Year: 2006
  • Published Articles: 2557

Full Length Research Paper

Adsorption in column of Cu (II), Ni (II) and Pb (II) with XAD-7 resin impregnated with bis (2-ethylhexyl) ammonium bis (2-ethylhexyl) dithiocarbamate (BEABEDC) in aqueous solution

R. Diouf1, S. A. Ndiaye1* and L. Muhr2
  1Department of Chemistry, Faculty of Sciences and Technology, Cheikh Anta Diop University, Senegal. 2LRGP, ENSIC-Nancy; 1 Rue Grandville; BP: 20451, 54001 Nancy Cedex, Senegal.
Email: [email protected]

  •  Accepted: 22 March 2011
  •  Published: 31 July 2011

Abstract

 

The extraction of copper, nickel and lead in mini-column pack of resin XAD-7, impregnated with BEABEDC was realized by varying the concentration of metallic solution, flow rate of elution in the case of copper in order to carry out the kinetic exchanges which govern the system. These experiments were carried out in acidic region. Extraction chromatography is combined with the spectrometer of atomic absorption for analysis of solution collected after extraction. The experimental data have been integrated into Langmuir adsorption model. Cu (II) can be desorbed using H2SO44M when the temperature is elevated to 50°C.

 

Key words: Extraction chromatography, Copper Lead, Nickel, mini-column, resin XAD-7 impregnated, langmuir adsorption model, BEABEDC.

Abbreviation

BEABEDC, Bis (2-ethylhexyl) ammonium bis (2-ethylhexyl) dithiocarbamate; H2SO4, Sulfuric acid.

Copyright © 2023 Author(s) retain the copyright of this article.

This article is published under the terms of the Creative Commons Attribution License 4.0

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