International Journal of
Physical Sciences

  • Abbreviation: Int. J. Phys. Sci.
  • Language: English
  • ISSN: 1992-1950
  • DOI: 10.5897/IJPS
  • Start Year: 2006
  • Published Articles: 2572

Full Length Research Paper

Hydrothermal synthesis and structural characterization of an organically-templated open-framework trimolybdates

Chinyere A. Anyama
  • Chinyere A. Anyama
  • Inorganic Materials Chemistry Laboratory, Department of Pure and Applied Chemistry, University of Calabar, P. M. B. 1115, Calabar, Nigeria
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Grace E. Iniama
  • Grace E. Iniama
  • Inorganic Materials Chemistry Laboratory, Department of Pure and Applied Chemistry, University of Calabar, P. M. B. 1115, Calabar, Nigeria
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Joseph O. Ogar
  • Joseph O. Ogar
  • Inorganic Materials Chemistry Laboratory, Department of Pure and Applied Chemistry, University of Calabar, P. M. B. 1115, Calabar, Nigeria
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Ayi A. Ayi
  • Ayi A. Ayi
  • Inorganic Materials Chemistry Laboratory, Department of Pure and Applied Chemistry, University of Calabar, P. M. B. 1115, Calabar, Nigeria
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  •  Received: 27 July 2015
  •  Accepted: 02 October 2015
  •  Published: 16 October 2015

References

Armatas NG, Allis DG, Prosvirin A, Carnutu G, O'Connor CJ, Dunbar K, Zubieta J (2008). Molybdophosphonate clusters as building blocks in the oxomolybdate-organodiphosphonate/Cobalt(II)-organoimine system. Structural influences of secondary metal coordination preferences and diphosphonate tether lengths. Inorg. Chem. 47:832.
 
Armatas NG, Ouellette W, Whitenack K, Pelcher J, Liu H, Romaine E, O'Connor CJ, Zubieta J (2009). Construction of Metal-Organic Oxides from molybdophosphonates clusters and copper bipyrimidine building blocks. Inorg. Chem. 48:8897-8910.
 
Asnani M, Kumar K, Duraisamy T, Ramanan A (2012). Crystallization of organically templated phosphomolybdate cluster-based solids from aqueous solution. J. Chem. Sci. 124:1275-1286.
 
Ayi AA, Burrows AD, Mahon MF, Sebastian VM (2013). A molybdenum diphosphonate network structure exhibiting reversible dehydration and selective uptake of methanol. Cryst. Eng. Comm. 15:9301-9303
Crossref
 
Barrer RM (1982). Hydrothermal Chemistry of Zeolites, Academic press, London.
 
Davis, Lobo (1992). Zeolite and molecular sieve synthesis, J. Chem. Mat. 4:756-768.
 
Francis RJ, O'Hare D (1998). The kinetics and mechanisms of the crystallization of microporous materials. J. Chem. Soc. Dalton Trans. 1998:3133-3148
 
Hagrman D, Zubieta J (1998). Organic-inorganic composite oxide phase: one-dimensional molybdenum oxide chains entrained within a three-dimensional complex cationic framework in ({Cu2(triazolate)2(H2O)2}Mo4O13). Chem. Commun. 1998:2005-2006.
 
Hagrman PJ, Hagrman D, Zubieta J (1999). Organic-Inorganic hybrid Materials: From "Simple" Coordination Polymers to Organodiamine-Templated Molybdenum oxide. Angew. Chem. Int. Ed. 38:2638-2684.
 
Hagrman PJ, Zubieta J (2000). Solid-state coordination chemistry: Influences of {M(terpyridyl)} (M = Ni(III), Cu(II), Ni(II)} subunits on molybdenum oxide structures. Inorg. Chem.39: 5218−5224.
 
Hubbard DJ, Johnston AR, Casalongue HS, Sarjeant AN, Norquist AJ. (2008). Synthetic Approaches for Noncentrosymmetric Molybdates. Inorg. Chem. 47:8518-8525
Crossref
 
Jones S, Liu H, Schmidtke K, O'Connor CC, Zubieta J, (2010). A bimetallic oxide ({Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2), Constructed from novel (Mo4O10(O3PR)4}n4n- chains. Inorg. Chem. Comm. 13:298.
 
Lysenko AB, Senchy G A, Lincke J, Lässig D, Fokin AA, Butova ED, Schreiner PR, Krautscheid H, Domasevitch KV (2010). Metal oxide-organic frameworks (MOOFs), a new series of coordination hybrids constructed from molybdenum (VI) oxide and bitopic 1,2,3-triazole linkers. Dalton Trans. 39:4223−4231.
 
Pope MT, Müller A (2001). Polyoxometalate Chemistry from Topology via Self-Assembly to Applications. Kluwer Academic: Dordrecht, Netherlands.
 
Randy S, Rarig J, Zubieta J (2001). Influences of secondary metal–ligand subunits on molybdenum oxide structures: the hydrothermal syntheses and structures of (M(tpytrz)2Mo4O13) (M = Fe, Co, Ni, Zn; tpytrz = tripyridyltriazine), (Ni(tpytrz)Mo2O7) and (Zn2(tpytrz)Mo2O8). Dalton Trans. 23:3446−3452.
 
Senchyk GA, Lysenko AB, Babaryk AA, Rusanov EB, Krautscheid H, Neves P, Valente AA, Gonçalves IS, Krämer KW, Liu SX, Decurtins S, Domasevitch KV (2014). Triazolyl−Based Copper−Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic Performance. Inorg. Chem. 53:10112−10121
Crossref
 
Sheldrick GM (2008). A short history of SHELX. Acta Cryst. 64:112.
 
Sierka M, Todorova TK, and Sauer J, Kaya S, Stacchiola D, Weissenrieder J, Shaikhutdinov S, and Freund H-J, (2007) Oxygen adsorption on Mo112… surface studied by ab initio genetic algorithm and experiment . J. Chem. Phys. 126:234710
 
Wu CD, Lu CZ, Zhuang HH, Huang JS (2002). Hydrothermal assembly of a novel three-dimensional framework formed by (GdMo12O24)9- anions and nine coordinated GdIII cations. J. Am. Chem. Soc. 124:3836-3837.
 
Xu Y, Xu JQ, Zhang KL, Zhang Y, You XZ (2000). Keggin unit supported transition metal complexes: Hydrothermal synthesis and Characterization of (Ni(2,2'-bipy)3)1.5(PW12O40Ni(2,2'-bipy)2(H2O))0.5H2O and (Co(1,10'-phen)3)1.5 (PMo12O40Co(1,10'-phen)2(H2O)))•0.5H2O. Chem. Comm. 2:153-154.
 
Zhang JW, Kan XM, Li XL, Luan J, Wang XL (2015). Transition metal carboxylate coordination polymers with amide-bridged polypyridine co ligands: assemblies and properties. Cryst. Eng. Comm. 17:3881-3907
Crossref
 
Zhang YY, Qi Y, Zhang Y, Liu ZY, Zhao YF, Liu ZM (2007). Synthesis, structure and magnetic properties of a new iron phosphonate-oxalate with 3D framework: (Fe(O3PCH3)C2O4)(0.5)(H2O)). Mat. Res. Bull. 42:1531.

 

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