Journal of
Developmental Biology and Tissue Engineering

  • Abbreviation: J. Dev. Biol. Tissue Eng.
  • Language: English
  • ISSN: 2141-2251
  • DOI: 10.5897/JDBTE
  • Start Year: 2009
  • Published Articles: 42

Full Length Research Paper

Synthesis, spectroscopy and biological studies of Nickel (II) complexes with tetradentate Schiff bases having N2O2 donor group

Anant Prakash1*, Mukesh Pal Gangwar2 and K. K. Singh3
1Inorganic Bioinorganic Research Laboratory, Department of Chemistry, Government Post Graduate College, Ranikhet-263645 (Uttarakhand) India. 2Department of chemistry, Mahatama Jyotiba Phule Rohilkhand University, Bareilly-243001(Uttar Pradesh) India. 3Shri Ram Murti Smarak College of Engineering and Technology (S. R. M. S. CET) Bareilly-243001 (Uttar Pradesh) India.
Email: [email protected]

  • Article Number - DB3FE0E10353
  • Vol.3(2), pp. 13-19, February 2011
  •  Accepted: 23 November 2010
  •  Published: 27 February 2011

Abstract

Complexes of nickel(II) of N,N’-disalicylidene-3,4-diaminotoluene(H2L1), N,N’-bis(3,5-di-tert-butylsalicylidene)-1,3-diaminopropane(H2L2),tetrathiafulvalene-N,N’-phenylene bis (salicylideneimine)(H2L3), o-hydroxybenzaldehyde, o-hydroxyacetophenone ethylene diamine (H2L4) and 1-phenylbutane-1,3-dionemono-S-methylisothio- semicarbazone with 5-phenylazo- o-hydroxybenzaldehyde (H2L5) have been synthesized and characterized by elemental analysis, electronic, (Infra-Red) IR, 1H NMR, magnetic susceptibility measurement, molar conductance and thermal studies. The complexes are found to be non- ionic in nature. The analytical studies show tetrahedral, square planar and octahedral geometries of the complexes. The complexes have been found to posses 1:1 (M:L) stoichiometry. The bioefficacy of the ligands and their complexes have been examined against the growth of bacteria in vitro to evaluate their anti-microbial potential.

Key words: Tetradentate Schiff base, Nickel (II) ions, N2O2 group, spectra.

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