African Journal of
Pure and Applied Chemistry

  • Abbreviation: Afr. J. Pure Appl. Chem.
  • Language: English
  • ISSN: 1996-0840
  • DOI: 10.5897/AJPAC
  • Start Year: 2007
  • Published Articles: 368

Full Length Research Paper

Biotransformation of n – phenyl cyclohexenylimide and 3, 5 – dinitrobenzoic acid

O. A. Owolodun1* and G. A. Olatunji2
1Chemistry Department, Sapati International School, P. M. B 1494, Ilorin, Nigeria. 2Chemistry Department, University of Ilorin, P. M. B 1515, Ilorin, Nigeria
Email: [email protected]

  •  Accepted: 17 November 2009
  •  Published: 30 April 2010

Abstract

N - phenyl cyclohexenylimide and 3,5 - dinitrobenzoic acid were subjected to biotransformation on maize fermenting system. These compounds were left for two weeks in the fermenting system and later extracted with a mixture of n - hexane, diethyl ether and ethanol. The TLC of the biotransformed products were carried out. The structures proposed for the isolated biotransformed products were based on FT - IR and NMR spectral data. One of the biotransformed products arose from the reduction of N - phenyl cyclohexenyl imide while decarboxylation of 3,5-dinitrobenzoic acid resulted in 1,3- dinitrobenzene.

 

Key words:  Biotransformation, N – phenyl cyclohexenyl imide, 3,5-dinitrobenzoic acid, fermenting system.