African Journal of
Pure and Applied Chemistry

  • Abbreviation: Afr. J. Pure Appl. Chem.
  • Language: English
  • ISSN: 1996-0840
  • DOI: 10.5897/AJPAC
  • Start Year: 2007
  • Published Articles: 368

Full Length Research Paper

Kinetics of thermal substitution reactions of some Chromium (III) -alkyl amine complexes in mixed solvent media

A. Rajendran1* and K. Anbalagan2
1Department of Chemistry, Sir Theagaraya College, Chennai- 620 021, Tamil Nadu, India. 2Department of Inorganic Chemistry, Pondicherry University, Puducherry-605 014, India
Email: [email protected]

  •  Accepted: 04 January 2010
  •  Published: 31 July 2010

Abstract

Molecular dynamics of the aquation reactions of the complexes [Cr(en)2Cl2]Cl, [Cr(tn)2Cl2]Cl, [Cr(tetren)Cl]Cl2, [Cr(pn)2Cl2]Cl, [Cr(trien)Cl2]Cl and [Cr(dien)Cl3] have been extensively studied in mixed solvent media. Kinetics and thermodynamic parameters have been evaluated and the results are interpreted carefully in the light of statistical and regression models.

 

Key words: Cr (III) complexes, molecular dynamics, aquation reaction, kinetic parameters, thermodynamic parameter, statistical model, regression model.

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